Francesco Avolio is a Member of the Working Group of the International Relations Commission of the National Forensic Council (Commissione Rapporti Internazionali UE del Consiglio Nazionale Forense). He has been Vice-Chairman at the International EU Law Committee Council Bar of Naples for 11 years.

Since 2000, Francesco Avolio has been a lawyer at a law firm dealing with national, European, international law and associated jurisprudence. Avolio holds a doctoral degree from the Federico II University (Università Federico II).